On the solubility of gases in liquid casting alloys
https://doi.org/10.21122/1683-6065-2023-1-32-34
Abstract
It has been shown that hydrogen and oxygen atoms cannot be present in the open pores of crystal lattices of base metals of casting alloys. The solubility of gases in liquid casting alloys is a nanostructured process. Hydrogen and oxygen atoms in melts are adsorbed by basic metal elemental nanocrystals. Nitrogen dissolves in liquid iron, nickel and chromium not in atomic form, but in the composition of elementary nanocrystals and nitride molecules. After deoxidation of molten casting alloys, the main gas dissolved in them is hydrogen.
About the Authors
E. I. MarukovichBelarus
Minsk, Belarus, 24, Ya. Kolasa str.
V. Yu. Stetsenko
Belarus
Minsk, Belarus, 24, Ya. Kolasa str.
A. V. Stetsenko
Belarus
Mogilev, Belarus, 43, Mira ave.
References
1. Kurdyumov A. V., Belov V. D., Pikunov M. V. i dr. Proizvodstvo otlivok iz splavov cvetnyh metallov [Production of castings from non‑ferrous metal alloys]. Moscow, Izd. Dom MISiS Publ., 2011, 615 p.
2. Marukovich E. I., Stetsenko V. Yu. Nanostrukturnaya teoriya metallicheskih rasplavov [Nanostructured metal melt theory]. Lit’e i metallurgiya = Foundry production and metallurgy, 2020, no. 3, pp. 7–9.
3. Antonova M. M. Svojstva gidridov metallov: spravochnik [Properties of metal hydrides: Reference]. Kiev, Naukova dumka Publ., 1975, 128 p.
4. Solncev Yu. P., Pryahin E. I. Materialovedenie [Materials science]. St. Petersburg, Himizdat Publ., 2017, 784 p.
5. Marukovich E. I., Stetsenko V. Yu., Stetsenko A. V. O raspredelenii ugleroda v austenite Fe‑C splavov [On carbon distribution in Fe‑C alloy austenite]. Lit’e i metallurgiya = Foundry production and metallurgy, 2022, no. 2, pp. 23–25.
6. Samsonova G. V. Svojstva elementоv[Properties of elements]. Moscow, Metallurgiya Publ., 1976, 660 p.
7. Konstanty vzaimodejstviya metallov s gazami [Metal‑Gas Interaction Constants]. Moscow, Metallurgiya Publ., 1987, 368 p.
8. Samsonova G. V. Fiziko‑himicheskie svojstva okislov [Physicochemical properties of oxides]. Moscow, Metallurgiya Publ., 1978, 472 p.
9. Marukovich E. I., Stetsenko V. Yu., Stetsenko A. V. Rastvorenie vodoroda v metallah i litejnyh splavah [Dissolution of hydrogen in metals and casting alloys]. Lit’e i metallurgiya = Foundry production and metallurgy, 2022, no. 3, pp. 53–57.
Review
For citations:
Marukovich E.I., Stetsenko V.Yu., Stetsenko A.V. On the solubility of gases in liquid casting alloys. Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY). 2023;(1):32-34. (In Russ.) https://doi.org/10.21122/1683-6065-2023-1-32-34