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The influence of acid treatment on the adsorption‑structural characteristics of filtering materials created based on steelmaking slag

https://doi.org/10.21122/1683-6065-2024-3-87-94

Abstract

Many industrial enterprises use electroplating processes that lead to the formation of water containing heavy metal ions such as chromium, copper, zinc, nickel, and others. Such water is a dangerous source of environmental pollution. Most heavy metal ions belong to hazard classes I–II, they have carcinogenic and mutagenic properties, and have a cumulative effect.

The literature analysis showed that there is positive experience in the use of steelmaking slags in the processes of cleaning contaminated water of various origins from heavy metals.

The study examines the effect of acid activation on the adsorption‑structural characteristics of filtering materials created based on steelmaking slag. It is shown that during the interaction of some acids with slag, new crystallographic phases are formed

on its surface, and contact with other acids leads to the leaching of ions and their transition to the aqueous phase. It has been established that during acid activation, the specific surface area increases by 57–132 times compared to the original material.

About the Authors

A. S. Panasyugin
Belarusian National Technical University
Belarus
Minsk, Belarus, 65, Nezavisimosti ave.


A. R. Tsyganov
Belarusian State Technological University
Belarus
Minsk, Belarus, 13a, Sverdlova str.


N. P. Masherova
Belarusian State Technological University
Belarus
Minsk, Belarus, 13a, Sverdlova str.


N. D. Pavlovsky
Grodno State Medical University
Belarus
Grodno, Belarus, 80, Gorkogo str.


V. A. Lomonosov
Scientific and Practical Center of the National Academy of Sciences of Belarus for Materials Science
Belarus

Minsk, Belarus, 19, Petrusa Brovki str.



References

1. Belov S. V., Barbinov F.A., Kozyakov A. F. [et al.]. Ohrana okruzhayushchej sredy [Environmental protection]. Moscow, Vysshaya shkola Publ., 1991, 339 p.

2. Lyashko I. I. Logisticheskie principy razrabotki strategii upravleniya vtorichnymi resursami [Logistic principles for developing a strategy for managing secondary resources]. Ekologiya i zdorov’e cheloveka. Ohrana vozdushnogo i vodnogo bassejnov. Utilizaciya othodov = Ecology and human health. Protection of air and water basins. Waste disposal: Sat. scientific art. XIII International scientificpractical conf. Kharkov, Rider Publ., 2005, pp. 188–193.

3. Vasiliev A. N., Tudel N. N. Tekhnologii preduprezhdeniya rasprostraneniya tyazhelyh metallov v okruzhayushchej srede [Technologies for preventing the spread of heavy metals in the environment]. Ekotekhnologiya i resursosberezhenie = Ecotechnology and resource saving, 2000, no. 2, pp. 36–44.

4. Amitan V. N., Potapova N. N. Regional’nye aspekty upravleniya resursosberezheniem [Regional aspects of resource saving management]. Menedzher. Vestnik DonGAU = Manager. Bulletin of DonGAU, 2002, pp. 115–120.

5. Proskuryakov V.A., Shmidt L. I. Ochistka stochnyh vod v himicheskoj promyshlennosti [Waste water treatment in the chemical industry]. Leningrad, Chimiya Publ., 1977, 464 p.

6. Clearfield A. Inorganic ion exchange materials. Florida, CRC Press, 1982, p. 290.

7. Alferova L.A., Nechaev A. P. Zamknutye sistemy vodnogo hozyajstva promyshlennyh predpriyatij, kompleksov i rajonov [Closed systems of water management of industrial enterprises, complexes and regions]. Moscow, Stroyizdat Publ., 1984, 412 p.

8. Kuznetsov Yu. V., Shchebetkovsky V. N., Trusov F. G. Osnovy ochistki vody ot radioaktivnyh zagryaznenij [Fundamentals of water purification from radioactive contamination]. Moscow, Atomizdat Publ., 1974, p. 360.

9. Lurie Yu. Yu. Analiticheskaya himiya promyshlennyh stochnyh vod [Analytical chemistry of industrial wastewater]. Moscow, Himiya Publ., 1984, 464 p.

10. Panasyugin A. S., Grigor’ev S. V., Teran A. I. et al. Izvlechenie iz vodnyh rastvorov ionov zheleza i svinca fil’truyushchej zagruzkoj, sozdannoj na osnove staleplavil’nogo shlaka [Extraction from aqueous solutions ions of iron and lead by filter loading, created on the basis of steel melting slag]. Lit’e i metallurgiya = Foundry production and metallurgy, 2018, no. 3, pp. 58–62.

11. Panasyugin A.S., Grigor’ev S. V., Teran A. I., Anufriev V. N. Izvlechenie iz vodnyh rastvorov ionov zheleza i nitrat ionov fil’trujushhej zagruzkoj, sozdannoj na osnove staleplavil’nogo shlaka [Extraction of iron and nitrate ions from aqueous solutions using a filter media created on the basis of steel-smelting slag]. Trudy 26‑j Mezhdunarodnoj nauchno‑tehnicheskoj konferencii «Litejnoe proizvodstvo i metallurgija 2018. Belarus’». Minsk, 17–18 oktyabrya = Proceedings of the 26th International Scientific and Technical Conference “Foundry and Metallurgy 2018. Belarus”. Minsk, october 17–18, pp. 58–63.

12. Tsyganov A. R., Panasyugin A. S., Teran A. I. Koncentrirovanie iz vodnyh rastvorov ionov Fe3+, Cu2+ i Pb2+ fil’truyushchimi zagruzkami, soderzhashchimi staleplavil’nuyu shlakovuyu fazu [Concentration of Fe3+, Cu2+ and Pb2+ ions from aqueous solutions with filter media containing a steel-smelting slag phase]. Prirodopol’zovanie i ekologicheskie riski = Nature management and environmental risks: scientific‑pract. conf., Minsk, June 5, 2019. Minsk, 2019, pp. 261–265.

13. Cherkasova T. Yu. Osnovy kristallografii i mineralogii [Fundamentals of crystallography and mineralogy]. Tomsk, Tomsk Polytechnic. univ. Publ., 2014, 207 p.


Review

For citations:


Panasyugin A.S., Tsyganov A.R., Masherova N.P., Pavlovsky N.D., Lomonosov V.A. The influence of acid treatment on the adsorption‑structural characteristics of filtering materials created based on steelmaking slag. Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY). 2024;(3):87-94. (In Russ.) https://doi.org/10.21122/1683-6065-2024-3-87-94

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ISSN 1683-6065 (Print)
ISSN 2414-0406 (Online)