Preview

On the issue of studying the corrosion resistance of zinc coatings, including their additional treatment with passivation and paint and varnish material

https://doi.org/10.21122/1683-6065-2025-3-120-128

Abstract

This paper presents a brief review of the results previously obtained by the authors in their studies of the chemical and granulometric composition of zinc‑containing dispersed waste (zinc dust) generated during the galvanizing of pipes and subsequent steam blowing. It also examines the influence of technological parameters such as the mixture composition and the temperature of thermodiffusion galvanizing on the thickness, structure, and properties of zinc coatings produced using thermodiffusion galvanizing in saturating mixtures based on zinc‑containing waste. Since the primary function of zinc coatings is corrosion protection, samples of zinc coatings based on both standard zinc powder and production waste were fabricated ina rotating container unit for comparative corrosion resistance testing in a salt spray chamber. It is well known that to enhance corrosion resistance, zinc coatings are commonly passivated and coated with paint materials. Some of the zinc‑coated samples were also subjected to additional treatments. The comparative salt spray chamber testing (ongoing at the time of writing) revealed that after 300 hours of exposure, the coatings produced from zinc‑containing waste only slightly underperformed in terms of protective properties compared to those made with standard zinc powder. Additional treatments, specifically passivation, nearly eliminated white rust formation. Furthermore, the use of a combined paint coating system (passivation + painting) ensured complete corrosion resistance for no less than 300 hours in the salt spray chamber.

About the Authors

N. I. Urbanovich
Belarusian National Technical University
Belarus

Minsk,
65, Nezavisimosti ave.



K. E. Baranovsky
Belarusian National Technical University
Belarus

Minsk, 
65, Nezavisimosti ave.



T. I. Bendik
Belarusian National Technical University
Belarus

Minsk, 
65, Nezavisimosti ave.



V. G. Dashkevich
Belarusian National Technical University
Belarus

Minsk,
65, Nezavisimosti ave.



G. F. Livshits
Belarusian National Technical University
Belarus

Minsk,
65, Nezavisimosti ave.



Ya. S. Puzynin
Belarusian National Technical University
Belarus

Minsk, 
65, Nezavisimosti ave.



V. G. Matys
Belarusian State Technological University
Belarus

Minsk,
13A, Sverdlova str.



References

1. Urbanovich N. I., Baranovsky K. E., Rosenberg E. V. [et al.] Issledovanie granulometricheskogo, himicheskogo i fazovogo sostavov othodov proizvodstva goryachego cinkovaniya [Investigation of granulometric, chemical and phase compositions of hotdip galvanizing wastes]. Lit’e i metallurgiya = Foundry production and metallurgy, 2021, no. 3, pp. 106–111.

2. Urbanovich N. I., Baranovsky K. E., Rozenberg E. V. [et al.] Analiz sposobov polucheniya cinksoderzhashchih pokrytij s primeneniem othodov proizvodstva goryachego cinkovaniya [Analysis of methods for obtaining zinc-containing coatings using hot-dip galvanizing production waste]. Lit’e i metallurgiya = Foundry production and metallurgy, 2021, no. 2, pp. 87–93.

3. Urbanovich N. I., Baranovsky K. E., Bendik T. I. [et al.] Issledovanie vliyaniya sostava nasyshchayushchih smesej so standartnym cinkovym poroshkom i cinkovoj pyl’yu na izmenenie razmerov i massy stal’nyh obrazcov pri termodiffuzionnom ih cinkovanii [Study of the influence of the composition of saturating mixtures with standard zinc powder and zinc dust on changes in the sizes and mass of steel specimens during their thermal diffusion zinc coating]. Lit’e i metallurgiya = Foundry production and metallurgy, 2023, no. 2, pp. 107–110.

4. Urbanovich N. I., Baranovsky K. E., Dashkevich V. G. [et al.] Issledovanie vliyaniya tekhnologicheskih parametrov termodiffuzionnogo cinkovaniya v sisteme Znотх–Al2O3 na svojstva i mikrostrukturu pokrytiya [Study of the influence of technological parameters of thermal diffusion galvanizing in the Znотх–Al2O3 system on the properties and microstructure of the coating]. Lit’e i metallurgiya = Foundry production and metallurgy, 2024, no. 1, pp. 78–82.

5. Urbanovich N. I., Baranovsky K. E. Sostav poroshkovoj smesi dlya termodiffuzionnogo cinkovaniya stal’nyh izdelij: patent № 24325 Resp. Belarus’, S23S 10/28 [Composition of the powder mixture for thermal diffusion galvanizing of steel products: patent No. 24325 Republic of Belarus, C23C 10/28].

6. Proskurkin E. V., Popovich V.A., Moroz A. T. Cinkovanie: spravochnik [Galvanizing: Handbook]. Moscow, Metallurgiya, 1988, p. 427.

7. Fishberg I. V. Sposob polucheniya zashchitnyh pokrytij: pat. 2148678 RF, MPK7 S 23 S 10/36, 10/60, 22/00. – № 98120846/02; zayavl. 20.11.1998, opubl. 10.05.2000 [Method for producing protective coatings: patent. 2148678 Russian Federation, IPC7 C 23 C 10/36, 10/60, 22/00 – No. 98120846/02; declared. 20.11.1998, published. 10.05.2000]. Oficial’nyj byul. Ros. agentstva po patentam i tovarnym znakam = Official Bulletin of the Russian Patent and Trademark Agency, 2000, no. 36, pp. 32.

8. GOST R 9.316-2006 Edinaya sistema zashchity ot korrozii i stareniya. Pokrytiya termodiffuzionnye cinkovye. Obshchie trebovaniya i metody kontrolya. Vved. 21.09.2006 [Unified system of protection against corrosion and aging. Thermodiffusion zinc coatings. General requirements and control methods]. Moscow, Standartinform, 2020, p. 17.

9. Official website of the company NPP «Ekomet» [Electronic resource]. Access mode: https://www.ecomet.ru.

10. Standard Practice for Preparation of Zinc (Hot-Dip Galvanized) Coated Iron and Steel Product and Hardware Surfaces for Painting ASTM D6386–16a, s. 5 https://www.standards.ru/document/6883035.aspx

11. Official website of OOO «Rem-Color» [Electronic resource]. Access mode: https://rem-color.by


Review

For citations:


Urbanovich N.I., Baranovsky K.E., Bendik T.I., Dashkevich V.G., Livshits G.F., Puzynin Ya.S., Matys V.G. On the issue of studying the corrosion resistance of zinc coatings, including their additional treatment with passivation and paint and varnish material. Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY). 2025;(3):120-128. (In Russ.) https://doi.org/10.21122/1683-6065-2025-3-120-128

Views: 13


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1683-6065 (Print)
ISSN 2414-0406 (Online)